A particle moves in x-y plane under the influence of a force \vec{F} such that its linear momentum is \overrightarrow{\mathrm{p}}(\mathrm{t})=\hat{i} \cos (\mathrm{kt})-\hat{j} \sin (\mathrm{kt}). If \mathrm{k} is constant, the angle between \overrightarrow{\mathrm{F}} and \overrightarrow{\mathrm{p}} will be :