At the interface between two materials having refractive indices n_1 and n_2, the critical angle for reflection of an em wave is \theta_{1C}. The \mathrm{n}_2 material is replaced by another material having refractive index n_3 such that the critical angle at the interface between n_1 and n_3 materials is \theta_{2 C}. If n_3>n_2>n_1 ; \frac{n_2}{n_3}=\frac{2}{5} and \sin \theta_{2 C}-\sin \theta_{1 C}=\frac{1}{2}, then \theta_{1 C} is :