The X-Y plane be taken as the boundary between two transparent media $\mathrm{M}_{1} and \mathrm{M}_{2}. \mathrm{M}_{1} in Z \geqslant 0 has a refractive index of \sqrt{2} and M_{2} with Z<0 has a refractive index of \sqrt{3}. A ray of light travelling in \mathrm{M}_{1} along the direction given by the vector \overrightarrow{\mathrm{P}}=4 \sqrt{3} \hat{i}-3 \sqrt{3} \hat{j}-5 \hat{k}, is incident on the plane of separation. The value of difference between the angle of incident in \mathrm{M}_{1} and the angle of refraction in \mathrm{M}_{2}$ will be __________ degree.
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