The equation of state of a real gas is given by $\left(\mathrm{P}+\frac{\mathrm{a}}{\mathrm{V}^2}\right)(\mathrm{V}-\mathrm{b})=\mathrm{RT}, where \mathrm{P}, \mathrm{V} and \mathrm{T} are pressure, volume and temperature respectively and \mathrm{R} is the universal gas constant. The dimensions of \frac{\mathrm{a}}{\mathrm{b}^2}$ is similar to that of :